Abstract

An individual vinyl cation in the form of a zwitterion stabilized by the 3-η 5-C 5H 5Fe 11-η 5-(3)-1,2-C 2B 9 H 10-1 group has been produced for the first time, and its reactions with nucleophilic agents have been studied. Deprotonation yielding an acetylene derivative is the main reaction in the interaction of the vinyl cation with MeLi, NaBH 4 and C 5H 5N.

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