Abstract
Methods for syntheses of new polyfluorinated compounds, viz., silanes containing substituents CF3CF2CF2C(CF3)2(CH2)3 (RF) at the silicon atom and 1,3,5-tris(RF)-1,3,5-trimethylcyclotrisiloxane that can be used for the synthesis of fluorocontaining oligo- and polysiloxanes of different structure, were developed. The polymerization of cyclotrisiloxane in the presence of 1,3-divinyltetramethyldisiloxane gave linear oligomers, whose chain contain -(RF)Si(Me)O- units.
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