Abstract

Abstract A series of cyanamido-bridged di- and tetraruthenium complexes with η6-C6Me6 ligands have been synthesized, and their interconversion reactions have been investigated. Facile interconversion between the μ2-κN,κN and μ2-κN,κN′ coordination modes of NCNH ligands at a dimetallic core has been observed for the first time.

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