Abstract
Abstract A new 2D zinc phosphate [H3NCH(CH3)CH2NH3]2+ 0.75[COOH(CH2)COOH]0.25(Zn3P3O11OH)2- * 0.5NH4 + consists of zinc phosphate layers, which are intercalated by diprotonated 1,2-diaminopropane, malonic acid, and NH4 + ions. The inorganic layers are composed of alternating ZnO4 and PO4 (PO3OH) tetrahedra that form 8-membered ring apertures. The intercalated species strongly interact with the zinc phosphate layers through hydrogen bonds, which is a key factor in stabilizing the structure. Crystal data: monoclinic, P21/a, a = 8.3457(1) Å, b = 16.8953(3) Å, c = 10.1817(2) Å, β = 95.3121(8)°, Z = 4, R = 0.0423.
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