Synthesis and self-assembly of brush-shaped block copolymer structure via ATRP and ROP

Abstract

Well-controlled brush-shaped block copolymers (BBCPs) of high molecular weight with polystyrene (PS) and polylactic (PLA) side chains, (poly (cis-5-norbornene-exo-2,3-dicarboximide-end poly (styrene)))-block-(poly (cis-5-norbornene-exo-2,3-dicarboximide-end poly (lactide))) (PNB- g -PS)- b -(PNB- g -PLA) were synthesized by combining atom transfer radical polymerization (ATRP) and ring opening polymerization (ROP). The synthesis of the (PNB- g -PS)- b -(PNB- g -PLA) was well-controlled with molecular weight and polydispersity index ( M n, GPC = 1310000 g mol - 1 and M w / M n (GPC) = 1.16). The SEM, XRD and DSC reveal that there are two immiscible cis-5-norbornene-exo-2,3-dicarboximide-end poly(styrene) (NB-PS) and cis-5-norbornene-exo-2,3-dicarboximide-end poly(lactide) (NB-PLA) phases in BBCP after self-assembly, which leads to partial crystallization. Moreover, the effect of the self-assembly temperature on morphology and reflectance of (PNB- g -PS)- b -(PNB- g -PLA) has been investigated. These (PNB-g-PS)-b-(PNB-g-PLA) exhibit obvious pearlescent appearance and wide band reflection after heat-treated at different temperatures (120 °C, 130 °C, 140 °C and 150 °C). Besides, with the increase of the self-assembly temperature, the domain spacing of (PNB- g -PS)- b -(PNB- g -PLA) decreases and the reflectance in visible range of (PNB- g -PS)- b -(PNB- g -PLA) increases. However, the self-assembly temperature does not significantly influence the reflection wavelength range of (PNB- g -PS)- b -(PNB- g -PLA). • A brush-shaped block copolymer was synthesized via ATRP and ROP. • The BBCP after self-assembly shows crystallization behavior. • The temperature of self-assembly can tune the domain spacing of BBCP. • The BBCPs exhibit obvious pearlescent appearance and wide band reflection after heat-treated at different temperatures.