Abstract
A novel guanosine derivative with a photoswitching property, 8-styryl-2′-deoxyguanosine was synthesized, and showed very rapid and efficient reversible E– Z photoisomerization upon illumination at specific wavelength. In addition, E– Z photoisomerization can be iteratively performed by alternate illumination with monochroic 254 nm and 370 nm light without any side reactions.
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