Abstract
A one-pot synthetic approach to form core-extended N,N'-disubstituted diaryl dihydrophenazine (DADHP) diradical dications (DRDCs) via chemical oxidation from aryl-substituted ortho-phenyldiamines is reported. The isolated N,N'-disubstituted DADHP DRDCs were reduced to their neutral counterparts with hydrazine. The model system featuring an unsubstituted fluorene aryl group, 2a, was tested as a photocatalyst for the polymerization of methyl methacrylate using organocatalyzed atom transfer polymerization (O-ATRP), which yielded a polymer with a controlled molecular weight and narrow polydispersity.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
