Abstract
Two simple colorimetric anion chemosensors 1 and 2 containing OH and CONH groups were synthesized and their recognition properties toward various anions were investigated by naked-eye observation, UV–vis and 1H NMR titration spectra. The experiment results showed that compound 1 was able to selectively recognize F − and AcO − through the formation of 1:1 hydrogen bonding complex, concomitant with a detectable color change (from colorless to pale yellow) during the recognition process. For compound 2, a noticeable color change was seen only in the case of F −, which was very similar to compound 1 in the molecular structure merely lack of a salicyloyl OH group. Additionally, compound 1 displayed a moderate binding affinity to H 2PO 4 − ( K a = 5.96 × 10 3 M −1). In contrast, there were no detectable interactions between compound 2 and H 2PO 4 −. In a word, the current studies suggested that a subtle change to receptor structure may lead to large and unpredictable differences to recognition behavior of receptor compound.
Published Version
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