Abstract
Syntheses of [M(P(O)(OMe) 2)(P(OMe) 3) 4] (M = Co, Rh, Ir) are reported and variable temperature 31P NMR studies on the iridium complex are described. Hydrogen reacts differently with the Ir and Rh complexes giving (IrH 2(P(O)(OMe) 2)(P(OMe) 3) 3] and [RhH(P(OMe 3) 4], respectively. The crystal and molecular structure of the novel compound [IrH(P(OMe) 3) 4(P(OMe) 2OSnMe 2Cl 2)][SnCl 3Me 2] is described.
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