Abstract
Convenient methods for the synthesis of functionalized organophosphorus compounds containing carbonyl groups as well as di- or trialkoxymethyl fragments attached to phosphorus, and their derivatives, starting from the available derivatives of trivalent phosphorus acids, are proposed, and some properties of the new functionalized organophosphorus compounds are presented. So, the alkylation and acylation reaction of (dialkoxymethyl) phosphonites and their analogs have been studied. It is found that the Arbuzov rearrangement of these compounds was accompanied by the phosphorus–carbon bond cleavage with unique retention of the three-coordinate phosphorus. © 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:352–372, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21024
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