Abstract
AbstractSyntheses for the new bis(2,2,6,6‐tetramethylpiperidino)(phosphanyl)alumanes, tmp2AlP(SiMe3)2, tmp2AlP(SnMe3)2 and (tmp2Al)2PPh are described along with spectroscopic characterization and X‐ray crystallographic structure determinations. In addition, the insertion reactions between tmp2AlP(SiMe3)2 and CO2, COS and CS2 are described and compared with the outcomes for CO2 insertion reactions with tmp2AlCl and tmp2AlMe. In the case of the amino‐phosphanyl‐alumane, the Al–P bond undergoes the insertion chemistry in contrast to Al–N bond insertions observed with tmp2AlCl and tmp2AlMe. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
