Abstract
Synthesis of (dppe)Pt(OMe)2(1)[dppe = 1,2-bis(diphenylphosphino)ethane] by NaOMe metathesis on the analogous dichloride is reported along with the thermal and carbonylation chemistry of (1); the release of dimethyl carbonate and dimethyl oxalate from the carbonylation product (dppe)Pt(CO2Me)2 was accomplished by thermal and oxidative techniques.
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