Abstract
Several thiocarboxamido complexes of manganese and molybdenum have been prepared by the reactions of metal carbonyl anions with dimethylthiocarbamoyl chloride, Me 2NCSCl. In these complexes the thiocarboxamido group is thought to be bound to the metal through both the carbon and sulfur atoms, acting as a three-electron donating ligand. The sulfur atom can be methylated without altering this mode of bonding. Reactions of some of these complexes with triphenylphosphine are described.
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