Abstract

The metallo-diethynylbenzene complex W(CC6H4CCH-4)(dmpe)2Cl, a precursor to metal-containing poly(phenyleneethynylene)s, has been prepared using alkyne-metathesis methodology and can be coupled into unsaturated organic frameworks at both the ethynyl moiety and the tungsten center and one-electron oxidized to the open-shell cation.

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