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Abstract
Lithium acetylide was reacted with adamantanone, verbanone, and verbenone to obtain their hydroxyethynyl derivatives whose reaction with aqueous ammonia solution of silver nitrate gave the corresponding polycycloaliphatic silver acetylides. The latter react with iodine, yielding hydroxyethynyl iodides. Acetates of the adamantane-containing ethynyl alcohols were prepared.
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