Abstract

Preparation et reactivite des complexes [MCl(cod)(o-Ph 2 PC 6 H 4 NHR)],M=Ir, Rh, cod=cyclooctadiene-1,5, R=CH 2 Rh,Et: addition de la pyridine ou de l'acetonitrile sur l'amine, pyrolyse et carbonylation. Etude radiocristallographique du complexe [IrHCl(o-Ph 2 PC 6 H 4 NHCH 2 Ph) 2 ]Cl-2CDCl 3

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