Synthesis and reaction chemistry of iridium(III) hydrides formed by the intramolecular nitrogen-hydrogen addition of hybrid phosphine amines to iridium(I)

Soonheum Park,M Pontier Johnson,D Max Roundhill

doi:10.1021/om00109a020

Synthesis and reaction chemistry of iridium(III) hydrides formed by the intramolecular nitrogen-hydrogen addition of hybrid phosphine amines to iridium(I)

Soonheum Park, M Pontier Johnson + Show 1 more

https://doi.org/10.1021/om00109a020

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Journal: Organometallics	Publication Date: Jul 1, 1989
Citations: 30

#Iridium Hydrides #Addition Of Amines + Show 6 more

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Abstract

Preparation et reactivite des complexes [MCl(cod)(o-Ph 2 PC 6 H 4 NHR)],M=Ir, Rh, cod=cyclooctadiene-1,5, R=CH 2 Rh,Et: addition de la pyridine ou de l'acetonitrile sur l'amine, pyrolyse et carbonylation. Etude radiocristallographique du complexe [IrHCl(o-Ph 2 PC 6 H 4 NHCH 2 Ph) 2 ]Cl-2CDCl 3

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