Synthesis and property of superabsorbent polymer based on cellulose grafted 2-acrylamido-2-methyl-1-propanesulfonic acid

Abstract

An eco-friendly superabsorbent polymer (SAP) was prepared by grafting 2-acrylamido-2-methyl-1-propanesulfonic acid onto microcrystalline cellulose in lithium chloride/N, N-dimethylacetamide system. The synthesized SAP (cellulose-g-PAMPS) was characterized by FTIR, TGA, SEM, 1H NMR, 13C NMR and XRD. The water absorption equilibrium of cellulose-g-PAMPS could be achieved within 10 min in distilled water. Moreover, the maximum water absorption capacities of cellulose-g-PAMPS in distilled water, 0.9 wt% NaCl solution and 3.2 wt% Na2CO3 solution were 648.9, 298.4 and 207.3 g·g−1, respectively. The water absorption behavior of cellulose-g-PAMPS was interpreted by the pseudo-second-order model. Furthermore, cellulose-g-PAMPS could be used in some extreme conditions due to its high acid and alkali resistance. The water retention rate of cellulose-g-PAMPS could be maintained above 90 % at 25 °C for 6 h. As a consequence, the synthesized SAP can be applied to increase the plant growth and survival time under drought conditions, even under saline alkali conditions.