Abstract

1. Tris[tris(trimethylsilylmethyl)stannyl]- and tris[tris(trimethylsilylmethyl)germyl] thallium, the first stable compounds containing Sn-Tl and Ge-Tl bonds, have been prepared by the reaction of the hydrides of tris (trimethylsilylmethyl)tin and tris (trimethylsilylmethyl)germanium with triethylthallium. 2. The Sn-Tl bond is attacked in the reactions of the stannylthallium compound with lithium, mercury, oxygen, bromine, ethyl bromide, ethanol, and other reagents.

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