Synthesis and properties of through‐space conjugated polymers based on cyano‐substituted poly(p‐arylenevinylene)s

Abstract

AbstractNew through‐space cyano‐substituted poly(p‐arylenevinylene)s containing a [2.2]paracyclophane unit were synthesized by the Knoevenagel reaction. Polymers 5 and 7 have cyano groups at α‐positions and β‐positions from the dialkoxyphenylene unit, respectively. Their optical and electrochemical behaviors were investigated in detail in comparison with their model compounds. Polymers 5 and 7 exhibited through‐space conjugation via the cyclophane units. Polymer 5 showed greenish blue emission (λmax = 477 nm) in diluted solution with fluorescence quantum efficiency (ϕF) of only 0.007, whereas polymer 7 emitted in the bluish green region (λmax = 510 nm) with ϕF of 0.32. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5979–5988, 2009