Abstract

The Sn 2P 2Se 6 single nanocrystallites embedded in a photopolymeric oligoetheracrylate host were manufactured. Structural and electrooptical investigations unambiguously show a possibility to obtain specimens which have properties similar to the properties of bulk single crystals. It was revealed that UV-hardening of the liquid photocompositions at temperatures allowing an incommensurate phase existence leads to an increase of the electrooptical coefficients. External electric field induces a partial crystallographic ordering of the embedded single crystallites of Sn 2P 2Se 6. After applying the electric fields of intensity higher than 16 kV/cm a saturation of the crystallographic ordering degree parameters as well as the electrooptical coefficients was observed. A temperature hysteresis of the electrooptical coefficient was also found.

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