Abstract
In this study, we synthesized of BiPO4 nanocrystals in diamagnetic glass (45PbO–45Bi2O3–8B2O3–2P2O5mol %) by melt quenching technique and studied its influence to glass Faraday rotation. The 9nm irregular BiPO4nanocrystals formed in glass and changed glass structure, spectral and properties through the characterization of X-ray diffraction, field Emission scanning electron microscopy, differential scanning calorimetry, UV–Vis optical absorption, Vicker's hardness and Verdet constant etc. The BiPO4 –induced local plasmon effect and bigger polarization gave glass improvements on optical cutoff wavelength, Faraday rotation and Vicker's hardness which is very attractive to magneto optical glass devices.
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