Abstract
Abstract Reaction of copper(I) thiocyanate with imino oximes 3-[[2-(alkylamino)ethyl]imino]-2-butanone oximes or 3-[[2-(dialkylamino)ethyl]imino]-2-butanone oximes, (abbreviated as Hdox-enRR′), gave a series of copper(II) complexes which consist of binuclear complexes [Cu2(dox-enRR′)2(NCS)2] with a thiocyanate anion coordinated to the copper(II) ion. The magnetic susceptibilities over the temperature range 77–320 K show a strong antiferromagnetic spin coupling through the N–O bridge for these complexes. The magnetic behavior can be explained by using the Bleaney–Bowers equation.
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