Abstract

Abstract The derivatives of 2-phosphaadamantane were obtained by the reaction of dienamine 1 with RPC12 compounds (1): The course of this reaction was studied by NMR. Structure of compoundr 2 war confirmed by means of X-Ray difraction. The reactions of these compounds were investigated. The chemical properties of compounds 2 were found to be strongly dependent on the nature of ademantane skeleton. All attempts to obtaine the phosphinyl-substituted carbanions from compounds 2 have failed.

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