Synthesis and preparation of poly (AM-co-AMPS)/GO nanocomposites hydrogel as a rheology modifier and fluid loss controller for use in oil well cementing

Abstract

The aim of the present work is to evaluate the influence of graphene oxide (GO) on copolymer nanocomposites hydrogel structure based on acrylamide (AM) and 2-acryloamido-2-methylpropane sulfonic acid (AMPS) in the presence of the N, N-methylene-bis-acryl-amide (NMBA) by the free radical copolymerization technique. The influence of poly (AM-co-AMPS)/GO as a rheology modifier along with fluid loss controller on the rheological and mechanical properties of brine cement slurry was also investigated. The characterization results confirmed the synthesis of AM monomer and AMPS and showed their grafting with GO surface. The poly (AM-co-AMPS)/GO hydrogel improved the rheological properties of the cement slurry as compared to conventional cement slurry. Furthermore, free water and fluid loss of cement slurry declined by adding the copolymer nanocomposites hydrogel at elevated temperatures. Moreover, not only the thickening time of cement slurry dropped but also, the compressive strength increased with a rise of nanocomposites hydrogel concentrations. However, the nanocomposite hydrogels showed a great effect on early compressive strength than the final compressive strength. The results of this investigation revealed the excellent performance of crosslinked structure of copolymer nanocomposites hydrogel due to the linking of sulfonated AMPS and AM on the surface of GO nanosheet in the attendance of NMBA. This renders greater stability to the cement slurry against salinity and temperature changing of well formations during cementing operation. Thus, poly (AM-co-AMPS)/GO as a suitable rheology modifier and property enhancer can be applied in oil well cementing.