Abstract

AbstractThe preparation and polymerization of representative 1‐(perfluoroacyl)aziridines were examined. Polymerization of the aziridines was induced by heat, by certain inorganic nucleophiles such as cyanide, fluoride, and chloride, and by organic bases. Certain other inorganic nucleophilic reagents such as KI and KBr effected the rearrangement of the 1‐(perfluoroacyl)aziridines to the isomeric 2‐perfluoroalkyl‐2‐oxazolines. A possible reaction mechanism involving anionic polymerization in competition with oxazoline formation was discussed.

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