Abstract

To broaden its photoresponse window, the new polysilane 2 with a pendant (tricyanovinyl)aniline group has been prepared by a facile post-tricyanovinylation reaction of the N,N-dialkylaniline-substituted polysilane precursor 1. A steady-state photoconductivity study showed that polysilane 2 has an extended photoresponse region from the traditional ultraviolet to the visible region compared with polysilane 1.

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