Abstract
Synthesis of 4-hydroxyborauracil and 4-hydroxy-3-methylborauracil, the first boron analogues of uracil, and comparison of their 1H and 13C NMR properties with those of uracil, are presented. The analyses of NMR-monitored boron compound–alcohol and boron compound–amine interactions pointed to the existence of sp 3-hybridized, B,B-bis-methoxyborauracils and pyridine-/ n-butylamine-borauracils ate-complexes in solution.
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