Synthesis and microwave absorption performance of heat-treated RF/SiO2 aerogels

Abstract

The well-designed composite with satisfactory electromagnetic microwave absorption at high temperatures remains a serious challenge. Herein, we fabricated a resorcinol-formaldehyde/silica dioxide composite aerogel (RF/SiO2) with a three-dimensional network structure using sol-gel, atmospheric pressure drying technique as well as heat-treated processes to achieve enhanced microwave absorption capabilities in the low frequency range. The pristine RF/SiO2 aerogel presented a typical micropores structure with a surface area, porous volume, and density of 146.82 m2/g, 62.40%, and 0.28 cm3/g, respectively. Remarkably, the RF/SiO2 aerogel showed an effective absorption bandwidth of 3.56 GHz and a minimum reflection loss value of −46.10 dB at 2.25 mm after being heat-treated at 1500 °C, while the maximum effective absorption bandwidth was 3.60 GHz at 2.30 mm. The intricate three-dimensional networks possessed remarkable impedance matching, multiple attenuation mechanisms, interfacial polarization, and dielectric loss, which were attributed to the exceptional ability to absorb electromagnetic microwaves. It offered a fresh approach to creating adaptable and effective microwave absorption materials in military defense.