Abstract

Four series of high birefringence biphenyl tolane liquid crystals having a terminal isothiocyanato or fluoro group were synthesized; their mesomorphic properties were studied by optical polarizing microscopy and DSC. These biphenyl tolane compounds exhibit reasonably low melting points and high birefringence of 0.37–0.49. By using these compounds a eutectic mixture was formulated exhibiting a wide nematic range, high figure‐of‐merit and low viscosity.

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