Synthesis and magnetic study for Fe-doped carbon nanotubes (CNTs)

Abstract

Aligned Fe-doped carbon nanotubes (CNTs) have been synthesized via pyrolyzing the ferrocene in 1050 °C. The Fe-doped CNTs had diameters of 40–80 nm and length up to ∼7 μm. Fe particles not only occurred at the tip of the CNTs, acting as the nuclei for CNTs growth, but also were doped on the surface of the CNTs or discontinuously encapsulated in the CNTs. Magnetic measurements showed that Fe-doped CNTs had ferromagnetically ordering temperature above room temperature and coercivities of 940 Oe at 5 K and 348 Oe at room temperature, respectively, which suggested that the aligned Fe-filled CNTs may have potential applications in data storage. Finally, a vapor–liquid–solid (V–L–S) mechanism was proposed for the aligned CNTs growth.