Abstract
The synthesis and magnetic properties of [M(Cp*)2][Ni(tds)2], M = Fe. Mn and Cr: tds = bis(trifluoromethyl)ethylenediselenato, are reported. The crystal structure for these compounds consists of an array of parallel stacks of alternating cations, [M(Cp*)2]±, and anions, [Ni(tds)2]−, ··D±A−D±A−D±A−··. For [Fe(Cp*)2][Ni(tds)2] and [Mn(Cp*)2][Ni(tds)2] the magnetic behavior is dominated by FM interactions, with Θ values of 10.6 and 24.6 K respectively, while for [Cr(Cp*)2][Ni(tds)2] the magnetic behavior is dominated by AFM interactions, with Θ = −86.4 K. [Mn(Cp*)2][Ni(tds)2], at low temperatures, shows a metamagnetic behavior. with TN = 2.1 K and HC = 60 G.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
