Abstract
AbstractTwo comb‐like copolymers (BIMT and PMB) composed of N‐2‐thiazolylmethacrylamide (NTMA) and 2‐(1‐butylimidazolium‐3‐yl) ethyl methacrylate tetrafluoroborate (BIMA) were prepared by free radical polymerization and reversible addition‐fragmentation chain transfer (RAFT) polymerization. The conversion of the monomers to copolymer has been confirmed by FTIR spectra and 1H NMR spectra. The metal (Ni2+, Nd3+) complexes of these two copolymers were prepared, and the magnetic behaviors of the complexes were studied. The coordinated complexes display three possible chelating structures, which lie on the nitrogen donor and oxygen donor ligands and the kinds of the metal ions. The bimetallic complexes (BIMT‐Nd‐Ni and PMB‐Nd‐Ni) were synthesized by using the different coordination sites of the polymers. The magnetic properties of the complexes show that different structures arising from the different preparations, the kinds and the contents of metal ions, and the state of the complexes can infect the exchange interaction between the metal ions and induce various magnetic phenomena. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5123–5132, 2008
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Polymer Science Part A: Polymer Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
