Synthesis and luminescent properties of Na5(La,Y) (MoO4)4: Sm3+ phosphors for solid-state lighting application

Abstract

The Sm3+ and La3+ co-doped Na5Y(MoO4)4 orange-red phosphors were synthesized by solid phase method at 600 °C. The crystal structure, phase purity, thermal stability, and luminescence performance were comprehensively analyzed. Under 405 nm excitation, the phosphors emit the orange-red light because of the 4G5/2-6H5/2, 4G5/2-6H7/2, 4G5/2-6H9/2, and 4G5/2-6H11/2 transitions of Sm3+ ions. The enhancement of emission intensity with La3+ ions doping in phosphors is due to the environmental effect of the crystal field around the luminous center. When it is combined with commercial LED chips, the device emits orange-red light, and the luminescence spectrum coincides with the PR pigment absorption spectrum of the plant, indicating that the potential of Sm3+ and La3+ co-doped Na5Y(MoO4)4 phosphors in solid-state lighting application.