Abstract

In this study, a single phase Mg(BH4)2 was chemically synthesized by means of the metathesis reaction of MgCl2 with NaBH4 in diethyl ether, and its hydrogen storage properties on dehydriding and rehydriding reactions were also investigated. These results provide valuable insights for hydrogen storage technologies. 2. Experimental The starting materials, anhydrous MgCl2 (95% purity) and NaBH4 (99.99% purity), were purchased from Aldrich Co., Ltd. The organic solvent of diethyl ether (dehydrated, CicaReagent) was purchased from Kanto Chemical Co., Inc. Mg(BH4)2 was synthesized by means of the metathesis reaction of MgCl2 with NaBH4 according to the following reaction. 28–30)

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