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Abstract
The synthesis of the new bulky tris[(phenyldimethylsilyl)methyl]tin hydride (9), tetrakis[(phenyldimethylsilyl)methyl]tin (5), and hexakis[(phenyldimethylsilyl)methyl]ditin (10) as well as some physical properties are described. The addition of hydride 9 to seven mono- and disubstituted alkynes under radical conditions indicates that these reactions take place with complete stereoselectivity. Full 1H, 13C, 119Sn, and 29Si NMR characteristics are included.
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