Synthesis and evaluation of different thio-modified cellulose resins for the removal of mercury (II) ion from highly acidic aqueous solutions

Abstract

Seven different types of thio- and/or amine-modified cellulose resin materials were synthesized and their mercury (II) ion adsorption properties determined. All seven resins showed good mercury (II) adsorption capability in the more neutral pH regions. However, the o-benzenedithiol- and o-aminothiophenol-modified cellulosic resins were found to be very effective in removing mercury (II) ions from strongly acidic media. For example, 93.5-100% mercury (II) ion recoveries from very acid aqueous solutions (nitric acid concentration ranged from 0.1 to 2.0 mol/L) were obtained using the o-benzenedithiol-modified resin while recoveries ranged from ca. 50% to 60% for the o-aminothiophenol-modified resin. An adsorption capacity of 23 mg (as Hg atoms) per gram of resin was observed for the o-benzenedithiol-modified cellulose in the presence of 1.0 mol/L nitric acid. This same resin shows very good selectivity for mercury (II) as only ruthenium (II) also somewhat adsorbed onto it out of 14 other metal ions studied (Ag(+), Al(3+), As(3+), Co(2+), Cd(2+), Cr(3+), Cu(2+), Fe(3+), Mn(2+), Ni(2+), Pt(2+), Pb(2+), Ru(2+), and Zn(2+)).