Abstract
A family of Mannich bases were prepared from the reaction of 2,2-bis-(4-hydroxyphenyl)propane (bisphenol A or BPA), formaldehyde, and poly(oxyalkylene)diamines at 1 : 1 : 1 or 1 : 2 : 2 molar ratio. By varying the molar ratio of bisphenol A to amine and the chemical structures of poly(oxyalkylene)diamines, a series of products with multiple functionalities of primary/secondary amines, phenols, and poly(oxyalkylene) were prepared. The curing profiles of these products toward the diglycidyl ether of bisphenol A (DGEBA) were examined by a differential scanning calorimeter (DSC). The physical properties of these cured materials were correlated with the chemical structures of the Mannich bases. Compared with the poly(oxyalkylene)diamines, the built-in phenol moiety in Mannich bases accelerated the curing rate. Both amine and phenol functionalities could be reactive sites toward diglycidyl ethers in a step-wise fashion under catalytic (triphenylphosphine) and different temperature conditions. Furthermore, the cured polymers demonstrated improved properties including tensile and flexural strength in comparison with those cured by the corresponding poly(oxyalkylene)diamines. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 615–623, 2000
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