Abstract

Conducting graphene oxide/polydiphenylamine (GO/PDPA) microsheet nanocomposite particles were fabricated via in-situ oxidative polymerization using diphenylamine in the presence of GO. The morphological structures and dimensions of the fabricated GO/PDPA composites were evaluated using transmission electron microscopy and scanning electron microscopy. Electrorheological (ER) responses and creep behaviors of an ER fluid consisting of the GO/PDPA composites when suspended in silicone oil were evaluated using a rotational rheometer under input electric field. Three different types of yield stresses were examined along with dielectric analysis, demonstrating their actively tunable ER behaviors.

Highlights

  • Intelligent and smart fluids have drawn widespread attentions from industries and academia because of their sensitivities to applied stimuli, including electric and magnetic fields, pressure, temperature, and light [1,2]

  • The increase in the shear viscosities, yield stresses, and viscoelastic moduli depends on the magnitude of the external electrical field strength; in this case, the ER fluids generally behave similar to a Bingham fluid or other types of non-Newtonian fluids

  • The PDPA uniformly adsorbed on the graphene oxide (GO) surface through π–π interactions

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Summary

Introduction

Intelligent and smart fluids have drawn widespread attentions from industries and academia because of their sensitivities to applied stimuli, including electric and magnetic fields, pressure, temperature, and light [1,2]. The tightly arranged chain-like structures can relax into an irregular liquid phase once the external electric field is removed; this process is repeatable, manageable, reversible, and instantaneous Owing to these valuable properties, they have numerous industrial applications in various fields, including those involving smart robots, anti-vibration systems, actuators, and food processing [6,7,8]. Conductive polymers with π-conjugated structures, such as PANI, have attracted considerable attention with regard to ER materials owing to their inherent polarizations, easy changes in conductivities, and low densities Their conductivities can be adjusted through doping or dedoping to achieve a suitable semiconducting range to avoid electrical short circuits under an external electric field. The ER responses and creep properties of a semiconducting GO/PDPA-composite-based ER suspension were tested

Materials and Synthesis
The monomer
Material Property
The response sensitivity and behavior behavior of the microsheet-based
Conclusions

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