Abstract

The complexes Re(L-L)(CO)3Cl with L-L = 9,10-phenanthrenequinone (PHQ) and 9,10- phenanthrenequinone diimine (PHI) were prepared and characterized spectroscopically. Both compounds show intense Re(I) to L-L metal-to-ligand charge transfer (MLCT) absorptions. In chloroform, the MLCT bands appear at 711 nm (L-L = PHQ) and 553 nm (L-L = PHI).

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