Abstract

The syntheses of nickel(II)porphyrins bearing palladium(II) or platinum(II) complexes at their periphery were performed. These new compounds were characterized by standard spectroscopic techniques and studied by electrochemistry. The electrochemical data were then compared with previously published data of porphyrin dimers linked by metal ions like palladium(II) or platinum(II). An X-ray structure of one of these species was obtained and confirmed the structure of this series of compounds.

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