Abstract
Synthesis dimethylglyoxime based heterotrimetallic macrocyclic complex was carried by taking the advantage of preferred coordination geometry of copper and chromium and selective use of sodium thiocyanate as axial ligand. The complex was characterized by elemental analysis, IR and MS. Magnetic behaviour of this complex, strong antiferromagnetic interactions were observed between metal ions which can be explained on the basis of spin orbit coupling. Electronic properties of the complex were studied using cyclic voltametry. Four well defined redox states were displayed in cyclic voltagram of which three were assigned to metal centers and one was ligand based redox state. On the other hand, the magnetic anisotropy due to different magnitude and nature of interactions in the complex makes it a possible single molecular magnet.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
