Abstract

Abstract The reaction of 1,3-bis[(4-chloro)benzene]triazene (HL) and [Pd(CH3CN)4]Cl2 gave a dinuclear triazenido complex Pd2L4 1, which has been characterized by 1H NMR spectrum and X-ray crystallography. Electrochemical studies showed that complex 1 is capable of generating hydrogen from acetic acid in DMF with icat/ip ~ 7.5.

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