Abstract
The title compound was synthesized in 3 steps (regioselective sulfenylation, m-CPBA and Pb(OAc) 4 oxidations) from N-Boc- p-anisidine. Its Diels-Alder reactions with cyclopentadiene took place on the double bonds C 2C 3 or C 5C 6 depending upon the experimental conditions with total endo-selectivity and high π-facial diastereoselectivity. The cycloaddition with trans-piperylene ocurred exclusively on the sulfinylsubstituted dienophilic double bond C 2C 3.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
