Abstract
AbstractThe enantioselective synthesis of zealexin A1, a sesquiterpene phytoalexin isolated from maize Zea mays is described for the first time. Our methodology for the total synthesis of zealexin A1 involved the stereoselective construction of the stereogenic center via enzymatic resolution followed by Johnson–Claisen rearrangement. The absolute configuration of the natural product was determined through gas chromatography analyses for the methyl esters for both synthetic and natural zealexin A1.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.