Abstract
AbstractBis(amino)silane bearing bulky substituents on nitrogen, LH2 [L = Me2Si(NDipp)2, Dipp = 2, 6‐diisopropylphenyl] was reacted with nBuLi (ratio 1:1 and 1:2) in toluene. The Me2Si(LiNDipp)2 was treated with SbCl3 in a 1:1 ratio to yield the four‐membered SiN2Sb ring compound of composition [η2(N,N)‐Me2Si(NDipp)2SbCl] (1). The mono lithiated bis(amino)silane was used to synthesize the monodentate heterotetraatomic complex [(η1‐Me2SiNDipp)NHDippSbCl2] (2) by the reaction with SbCl3. The complexes were characterized by 1H and 13C NMR, elemental analysis, IR, and single‐crystal X‐ray structural analysis.
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