Abstract
Abstract Two different complexes were obtained from (dmpp) and Cd(II) ions with the aid of pseudohalide ions in non-aqueous solvents. The dinuclear complex formed with thiocyanate ions show, using XRD, to posses two 1.3 bond μ bridges [CdL(SCN)2]2. The other dinuclear complex was also seen to form with cyanate ions but with the μ-bridge in a 1.1 position [CdL(OCN)2]. All Cd atoms are located in a distorted octahedral environment in 1 and 2 complexes. The Cd…Cda distances are 6.032(4) Å in 1 and 3.704(3) Å in 2, respectively. The N—C—S and O—C—N angles are approximately linear as 178.1(3) and 178.6(3)° in 1 and 177.2(5) and 176.9(7)° in 2, respectively. The Cd—(μ N,S-NCS)2—Cda bonds form a zig-zag structure in 1 and the Cd—(μ O,N-OCN)2—Cda bonds form a distorted square planar in 2.
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