Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Alexander G Medvedev,Mikhail Yu Sharipov,Dmitry A Grishanov,Artur V Eshtukov,Andrei V Churakov,Ivan A Buldashov,Pavel A Egorov,Ovadia Lev,Petr V Prikhodchenko

doi:10.1016/j.mencom.2022.01.018

Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Alexander G Medvedev, Mikhail Yu Sharipov + Show 7 more

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https://doi.org/10.1016/j.mencom.2022.01.018

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Journal: Mendeleev Communications	Publication Date: Jan 1, 2022
Citations: 6

Affiliation: NS Kurnakova Institute of General and Inorganic Chemistry, Hebrew University of Jerusalem, State Research Institute for Chemistry and Technology of Organoelement Compounds

#Peroxide In Benzene #Organic Peroxides + Show 8 more

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Abstract

Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

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