Abstract
A cluster complex of the composition [Th(DMSO)8Cl][Re6Se7Cl7] has been obtained by interaction of ThCl4 solution in DMSO with a water solution of K3[Re6Se7Cl7] and KCl. The compound crystallizes in the rhombic space group Pbcm with unit cell parameters a = 12.262(2) A, b = 19.653(6) A, c = 23.603(6) A, V = 5688(2) A3, Z = 4, d calc = 3.282 g/cm3. The structure is built from centrosymmetric cluster anions [Re6Se7Cl7]3− and complex cations [Th(DMSO)8Cl]3+ possessing mirror-plane symmetry, half of the DMSO ligands being doubly disordered.
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