Abstract
The new polymeric compound Fe(thiazole) 2Cl 2 ( 1) has been synthesised by the addition of thiazole to an ethanolic solution of anhydrous FeCl 2 The structure of Cu(tz) 2Br 2 ( 2) has also been determined. The structures of both polymers consist of pseudo-octahedral units, doubly linked by halide-bridges to form infinite linear chains. Slight variation in the bonding of the two are observed, relating to the Jahn-Teller nature of Cu 2+. Room temperature magnetic susceptibility measurements of 1 give an effective moment of 5.51(2) B.M., indicating high-spin Fe(II).
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