Abstract
The heterotrimetallic complex [Cu{trans-Pt(NH3)2(NHCOtBu)2}2](NO3)2 was synthesized and structurally characterized by X-ray crystallography. The cationic complex consists two trans-[Pt(NH3)2(NHCOtBu)2] units and one Cu2+ ion, which are linearly held together by four bridging pivalamidate ligands. The compound crystallizes in the monoclinic space group P21/c with a = 13.18(1) A, b = 13.12(1) A, c = 21.38(2) A, β = 116.88(3)°A, V = 3674(5) A3, and Z = 4. The trimeric Pt–Cu–Pt cation further aggregates into a dimer of trimer via a weak Pt···Pt interaction. Synthesis and crystal structure of pivalamidate-bridged trinuclear platinum–copper complex with a linear Pt–Cu–Pt core Chao Chen, Huayu Qiu*, Fenghui Liu and Wanzhi Chen* A heterotrimetallic complex [Cu{trans-Pt(NH3)2(NHCOtBu)2}2](NO3)2 was synthesized and structurally characterized by X-ray crystallography.
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